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Preheat oven to 425 degrees and spray a muffin tin with cooking spray or line with liners. Set aside.
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In a large mixing bowl, add in your buttermilk, oil, and eggs one at a time. Mix everything together.
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Slowly add in the flour, and all of your spices.
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Fold in your baking powder, shredded cheese, and pepperonis.
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Fill your muffin tin ¾ of the way and bake for 5 minutes.
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Turn down the oven temperature to 375 degrees and bake for another 10-11 minutes. Allow the muffins to completely cooling before removing from the muffin tin.